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This book provides a physics-oriented introduction to organogels with a comparison to polymer thermoreversible gels whenever relevant. The past decade has seen the development of a wide variety of newly-synthesized molecules that can spontaneously self-assemble or crystallize from their organic or aqueous solutions to produce fibrillar networks, namely organogels, with potential applications in organic electronics, light harvesting, bio-imaging, non-linear optics, and the like. This compact volume presents a detailed outlook of these novel molecular systems with special emphasis upon their thermodynamics, morphology, molecular structure, and rheology. The definition of these complex systems ...
Crystallisable polymers represent a large share of the polymers used for manufacturing a wide variety of objects, and consequently have received continuous attention from scientists these past 60 years. Molecular compounds from crystallisable polymers, particularly from synthetic polymers, are receiving growing interest due to their potential application in the making of new materials such as multiporous membranes capable of capturing large particles as well as small pollutant molecules. Polymer-Solvent Molecular Compounds gives a detailed description of these promising systems. The first chapter is devoted to the presentation of important investigational techniques and some theoretical appr...
This book aims to present the concept of Solvent Engineering within a broad scope, ranging from mixtures of solvents to achieve the desired solvation properties, to stimuli-responsive solvents. It covers diverse aspects such as thermodynamics and transfer phenomena associated with solvent engineering, as well as applications found in recent literature, spanning materials across science, biochemistry, chemistry, and separation and purification processes, among others. Solvent engineering is proposed as an innovative strategy to address environmental concerns related to the use of volatile and toxic solvents. This book highlights efforts to develop engineered solvents that offer more environmentally acceptable alternatives as against those currently in use.
This volume contains the proceedings of the 3rd International Conference on Polymer-Solvent Complexes and Intercalates held in Besancon, France in August 2000. As the reader will discover, results from various topics involving polymers, polyelectrolytes, polymer-like systems (self-assembling molecules, biological molecules), surfaces etc. were presented and discussed. They highlight the growing impact of this field on various scientific domains, and also the building of a scientific community concerned by the same questions.
This book contains selected contributions of the symposium "Second International Conference on Polymer-Solvent Complexes and Intercalates" held in Ischia in August 1998. In detail many aspects of the polymer-solvent interactions and dynamics in solids, surfaces, gels and solutions are discussed. Polymer chemists and physicists will find this volume invaluable in updating their information and increasing their understanding in this important area.
This volume contains papers based on the main lectures, oral communications and selected posters presented at the 4th International Conference of Polymer-Solvent Complexes and Intercalates held as the 63rd meeting of Prague Meetings on Macromolecules in Prague in July 2002. Many aspects of the polymer-solvent interactions, structure and dynamics in solution, gels, solids and interfaces are discussed in detail herein. The wide scope of the presented results is evidence of the growing impact of this field on various research areas.
With a focus on structure-property relationships, this book describes how polymer morphology affects properties and how scientists can modify them. The book covers structure development, theory, simulation, and processing; and discusses a broad range of techniques and methods. • Provides an up-to-date, comprehensive introduction to the principles and practices of polymer morphology • Illustrates major structure types, such as semicrystalline morphology, surface-induced polymer crystallization, phase separation, self-assembly, deformation, and surface topography • Covers a variety of polymers, such as homopolymers, block copolymers, polymer thin films, polymer blends, and polymer nanocomposites • Discusses a broad range of advanced and novel techniques and methods, like x-ray diffraction, thermal analysis, and electron microscopy and their applications in the morphology of polymer materials
Thermoreversible gelation is a comparatively new and growing area of polymer science. It encompasses many different systems from synthetic polymers to biopolymers. Abundant literature on the subject is scattered in many different journals, but this is the first book to gather together the current knowledge on both polymer and biopolymers thermoreversible gels. A multidisciplinary approach is taken, and extensive coverage of experimental results from electron and optical microscopy, light scattering and (new or neuron) diffraction techniques is provided. The book is organized into three main sections: Gel formation, thermal behavior and phase diagrams Gel morphology and molecular structure, gelation mechanisms Mechanical properties Polymers and bipolymers are treated separately in each section. The text is supplemented by four appendices: Phase diagrams Diffraction by helices Scattering by semi-rigid macromolecules; and elasticity of rigid networks
A look at all aspects of polymer– and biopolymer–solvent interactions, structure and dynamics in solutions, gels, solids and interfaces.