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Polymer science is a technology-driven science. More often than not, technological breakthroughs opened the gates to rapid fundamental and theoretical advances, dramatically broadening the understanding of experimental observations, and expanding the science itself. Some of the breakthroughs involved the creation of new materials. Among these one may enumerate the vulcanization of natural rubber, the derivatization of cellulose, the giant advances right before and during World War II in the preparation and characterization of synthetic elastomers and semi crystalline polymers such as polyesters and polyamides, the subsequent creation of aromatic high-temperature resistant amorphous and semi-...
The Second Winter School on the "~hysics of Finely Divided Matter" was held at the Centre de Physique des Houches from 25 March to 5 April 1985. This meeting brought together experts from the areas of gels and porous media. People with different backgrounds - chemists, physicists - from university as well as industrial labora tories, had the opportunity to compare their most recent experimental and theoreti cal results. Although the experimental situations and techniques may seem at first sight unrelated, the theoretical interpretations are very similar and may be divided roughly into two categories: percolation and aggregation. These are present for the description of the synthesis of some ...
This book contains the plenary lectures from international experts, which were presented during the International Conference Polymer Networks, held in Moscow, April 1991. The book covers different areas of physics and chemistry of polymer networks, generated by the formation of chemical bonds. New theoretical and experimental results concerning the synthesis, structure and properties of such networks as recently obtained in scientific centres world-wide are extensively presented.
Advanced composite materials or high performance polymer composites are an unusual class of materials that possess a combination of high strength and modulus and are substantially superior to structural metals and alloys on an equal weight basis. The book provides an overview of the key components that are considered in the design of a composite, of surface chemistry, of analyses/testing, of structure/property relationships with emphasis on compressive strength and damage tolerance. Newly emerging tests, particularly open hole compression tests are expected to provide greater assurance of composite performance. This publication is an "up-to-date" treatment of leading edge areas of composite technology with literature reviewed until recently and includes thermoplastic prepregs/composites and major application areas.
Large numbers of chemical engineers work with polymerization reactions and the problems and the challenges particular to the production of polymers. These problems have no counterparts in small-molecule reactions, and thus usually are neglected in standard reactor courses. This book provides a clearly written, comprehensive textbook on polymerization reactor engineering, appropriate for senior-level undergraduate and 1st- and 2nd-year graduate students. It focuses on polymer structure and structure-property relationships conditions that can play a role in dictating stucture.
For several decades, polymer science has sought to rationalize the mechanical and thermodynamic properties of polymer networks largely within the framework of statistical thermodynamics. Much of this effort has been directed toward the rubbery rather than the glassy state. It is generally assumed that networks possess an av erage composition to which average properties may be assigned; from such a continuum view, a powerful analysis of such properties as modulus, swelling, birefringence and thermoelasticity has emerged. In the years following the rise of polymer characterization (the late 40's and early 50's), many scientists began to study ap parent relations between the properties of linea...
This first-of-its-kind publication reviews the most impor-tant literature on the synthesis, properties, and applications of telechelic polymers. Written by a group of internationally known ex-perts in the field, this text contains a review table which allows the reader to search for given polymers with given end groups. Over 1,250 references are listed, covering primary and review articles as well as patents. Chapters include the preparation of telechelics by stepwise polymerization, anionic polymerization, radical polymer-ization, cationic polymerization, ring-opening polymerization and controlled polymer degradation. Polyols for the polyurethane pro-duction are described, as well as halato-telechelic polymers. Also, a more theoretical contribution on the physical properties of net-works formed from telechelic polymers is provided.
In celebration of Allan Hoffmana ‘s 70th birthday, a symposium entitled Gels, Genes, Grafts and Giants was held in Maui in December 2002. This symposium, organized by The University of Washington Engineered Biomaterials (UWEB) NSF Engineering Research Center, was a great success, with many excellent papers presented by scientists from all over the
This publication discusses the theoretical aspects of absorbency as well as the structure, properties and performance of materials. The chapters are arranged in an approach for the reader to advance progressively through fundamental theories of absorbency to more practical aspects of the technology. Topics covered include scientific principles of absorbency and structure property relationships; material technology including super absorbents, non-woven, natural and synthetic fibres and surfactants; absorbency measurement techniques and technology perspective. The reader is provided with current status information on technology and is also informed on important developments within the field.
Very thin film materials have emerged as a highly interesting and useful quasi 2D-state functionality. They have given rise to numerous applications ranging from protective and smart coatings to electronics, sensors and display technology as well as serving biological, analytical and medical purposes. The tailoring of polymer film properties and functions has become a major research field. As opposed to the traditional treatise on polymer and resin-based coatings, this one-stop reference is the first to give readers a comprehensive view of the latest macromolecular and supramolecular film-based nanotechnology. Bringing together all the important facets and state-of-the-art research, the two well-structured volumes cover film assembly and depostion, functionality and patterning, and analysis and characterization. The result is an in-depth understanding of the phenomena, ordering, scale effects, fabrication, and analysis of polymer ultrathin films. This book will be a valuable addition for Materials Scientists, Polymer Chemists, Surface Scientists, Bioengineers, Coatings Specialists, Chemical Engineers, and Scientists working in this important research field and industry.