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The chemoselective oxidation of vicinal diols to α-hydroxyketones is a challenge in organic syntheses because not only does the diol need to be oxidized selectively to a monocarbonyl compound, but diols are also prone to overoxidation and oxidative cleavage. Employing a cationic palladium complex, [(neocuproine)Pd(OAc)]2(OTf)2, we were able to demonstrate the selective oxidation of glycerol to dihydroxyacetone mediated by either benzoquinone or O2 as the terminal oxidant, an accomplishment that has little precedent in homogeneous catalysis. Mechanistic studies were undertaken to uncover the nature of this remarkable chemoselectivity. Kinetic and deuterium-labeling studies implicate reversib...
Covering American transgender history from the mid-twentieth century to today, Transgender History takes a chronological approach to the subject of transgender history, with each chapter covering major movements, writings, and events. Chapters cover the transsexual and transvestite communities in the years following World War II; trans radicalism and social change, which spanned from 1966 with the publication of The Transsexual Phenomenon, and lasted through the early 1970s; the mid-'70s to 1990-the era of identity politics and the changes witnessed in trans circles through these years; and the gender issues witnessed through the '90s and '00s. Transgender History includes informative sidebars highlighting quotes from major texts and speeches in transgender history and brief biographies of key players, plus excerpts from transgender memoirs and discussion of treatments of transgenderism in popular culture.
"Irene Taviss Thomson gives us a nuanced portrait of American social politics that helps explain both why we are drawn to the idea of a 'culture war' and why that misrepresents what is actually going on." ---Rhys H. Williams, Professor and Chair, Department of Sociology, Loyola University Chicago "An important work showing---beneath surface conflict---a deep consensus on a number of ideals by social elites." ---John H. Evans, Department of Sociology, University of California, San Diego The idea of a culture war, or wars, has existed in America since the 1960s---an underlying ideological schism in our country that is responsible for the polarizing debates on everything from the separation of ...
Philosophy of physics is concerned with the deepest theories of modern physics - quantum theory, our theories of space, time and symmetry, and thermal physics - and their strange, even bizarre conceptual implications. This book explores the core topics in philosophy of physics, and discusses their relevance for both scientists and philosophers.
Better therapy of acute leukemias depends ultimately on better understanding of the distinction between leukemic and normal progenitor cells. This hugely important new book describes the current knowledge of acute leukemia biology and discusses new classification systems that have arisen as a result of emerging insights into pathogenesis. Estey, Faderl and Kantarjian, who all work at the respected Anderson Cancer Center in Houston, Texas, USA, examine in detail advances in the treatment of particular types of acute leukemia. Their book also covers the management of acute leukemia in general as well as the development of new therapies. This book will be extremely useful to clinicians.
This breathtakingly broad, interdisciplinary reader demonstrates how widely feminist thinking has spread, how deeply it has shaken settled assumptions in the disciplines and how much new light it throws on contemporary controversies. - Myra Marx Ferree, University of Wisconsin-Madison "A timely intervention and highly engaged, thoughtful and scholarly analysis of the state of gender and women′s studies in the West by three eminent feminist scholars... Highly cognisant of the central issues that have fractured, blocked and enhanced western feminism." - Bev Skeggs, Goldsmiths "The comprehensiveness and the interdisciplinary range of themes are impressive, and they make the Handbook into a wo...
Published in conjunction with an exhibition held at the Boise Art Museum, Boise, Idaho, Oct. 9, 2010-Apr. 17, 2011.