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Ester Formation and Hydrolysis and Related Reactions
Physical Organic Chemistry—II provides information pertinent to the fundamental aspects of physical organic chemistry. This book discusses the common phenomenon in ionic organic chemistry. Organized into seven chapters, this book begins with an overview of electrochemical methods to obtain thermodynamic information on unstable species. This text then presents a brief summary of the experimental method in low temperature photochemical studies. Other chapters consider the general approach to understanding the molecular basis of enzyme catalysis and regulation. This book discusses as well the reactivity model for concerted cycloaddition reactions, which allows a systematization of substituent effects. The final chapter deals with the relative stabilities of phosphoranes in terms of the relative apicophilicities of groups, ring strain and steric factors, and experiments. This book is a valuable resource for organic and inorganic chemists. Postdoctoral students and scientists who are interested in physical organic chemistry will also find this book extremely useful.
Advances in Inorganic Chemistry
Advances in Organometallic Chemistry
The transItIOn-state theory has been, from the point of its inception, the most influential principle in the development of our knowledge of reaction mechanisms in solution. It is natural that as the field of biochemical dynamics has achieved new levels of refinement its students have increasingly adopted the concepts and methods of transition-state theory. Indeed, every dynamical problem of biochemistry finds its most elegant and economical statement in the terms of this theory. Enzyme catalytic power, for example, derives from the interaction of enzyme and substrate structures in the transition state, so that an understanding of this power must grow from a knowledge of these structures and...
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The A...
The only book series to summarize the latest progress on organic reaction mechanisms, Organic Reaction Mechanisms, 1971 surveys the development in understanding of the main classes of organic reaction mechanisms reported in the primary scientific literature in 1971. The 7th annual volume in this highly successful series highlights mechanisms of stereo-specific reactions. Reviews are compiled by a team of experienced editors and authors, allowing advanced undergraduates, graduate students, postdocs, and chemists to rely on the volume's continuing quality of selection and presentation.
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The first seven metals in the periodic table are lithium, beryllium, sodium, magnesium, aluminium, potassium and calcium, known collectively as the “lightest metals”. The growing uses of these seven elements are enmeshing them ever more firmly into critical areas of 21st century technology, including energy storage, catalysis, and various applications of nanoscience. This volume provides comprehensive coverage of the fundamentals and recent advances in the science and technology of the lightest metals. Opening chapters of the book describe major physical and chemical properties of the metals, their occurrence and issues of long-term availability. The book goes on to disucss a broad range...