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The rheology of polymer melts plays an important role today in industry and academia. Although several textbooks on this subject are available, with very few exceptions they cover homogeneous products only. This book is unique in that it focuses on heterogeneous systems such as particle-filled materials and polymer blends, which are highly important in the world market. It deals with similarities and differences of the flow properties of these two classes of material, providing both a fundamental and a practical understanding. Key points of the book are the viscous and elastic properties of engineering polymers filled with functional particles and the influence of nanoparticles on rheological properties. Two key aspects of rheological measurements are discussed: the influence of heterogeneous structures on the flow of materials important for processing and the use of rheological means to get an insight into morphological features. Both approaches are applied to particle-filled melts and to polymer blends. In the latter case it is shown in detail in which way the deformation of droplets formed by the dispersed phase can be affected by outer deformation, particularly in elongation.
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This book describes the properties of single polymer molecules and polymeric materials and the methods how to characterize them. Molar masses, molar mass distributions and branching structure are discussed in detail. These properties are decisive for a deeper understanding of structure/properties relationships of polymeric materials. This book therefore describes and discusses them in detail. The mechanical behavior as a function of time and temperature is a key subject of the book. The authors present it on the basis of many original results they have obtained in their long research careers. They present the temperature dependence of mechanical properties of various polymeric materials in a...
Understanding the elastic properties of polymer melts is necessary for ensuring successful polymer processing and thus producing high-quality plastic parts. This unique book is the first to focus on this important topic. Starting with the molecular origin of elastic behavior and an explanation of the physical quantities involved, experimental methods and the dependence of elastic behavior on experimental parameters are then presented. Elastic properties of filled and unfilled systems are compared directly, and polymer blends are also considered. Elastic effects in various applications are included, such as in extrudate swell, internal stresses, and shrink films, to illustrate the importance of this field in the plastics processing industry.
Explore polymer rheology from an industrial standpoint Presenting state-of-the-art polymer rheology as observed by well-recognized authors, Applied Polymer Rheology: Polymeric Fluids with Industrial Applications is designed to help readers understand the relationship between molecular structure and the flow behavior of polymers. In particular, it focuses on polymeric systems that elicit special attention from industry. Providing a comprehensive overview of the rheological characteristics of polymeric fluids, the book bridges the gap between theory and practice/application, enabling readers to see the connection between molecular structure and the behavior of the polymers studied. Beginning w...
The science of rheology remains a mystery to most people, even to some scientists. Some respectable dictionaries have been quite cavalier in their attitude to the science, the small Collins Gem dictionary, for example, being quite happy to inform us that a Rhea is an three-toed South American ostrich, whilst at the same time offering no definition of rheology. This maybe due to the fact that the science is interdisciplinary and does not fit well into any one of the historical disciplines. This book contains an in-depth study of the history of rheology, beginning with the statements of Heraclitus, Confucius and the prophetess Deborah. It also emphasises the distinctive contributions of Newton...