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Ionic liquids have attracted considerable interest in recent years. In this book the bulk and interfacial physico-chemical characteristics of various fluid systems dominated by Coulomb interactions are treated which includes molten salts, ionic liquids as well as metal-molten salt mixtures and expanded fluid metals. Of particular interest is the comparison of the different systems. Topics in the bulk phase concern the microscopic structure, the phase behaviour and critical phenomena, and the metal-nonmetal transition. Interfacial phenomena include wetting transitions, electrowetting, surface freezing, and the electrified ionic liquid/ electrode interface. With regard to the latter 2D and 3D electrochemical phase formation of metals and semi-conductors on the nanometer scale is described for a number of selected examples. The basic concepts and various experimental methods are introduced making the book suitable for both graduate students and researchers interested in Coulombic fluids.
Several state-of-the-art applications of molten salts are presented, such as metal-molten salt systems, room temperature glass formation, and room temperature melts. Several recent examples of applications highlight the importance of molten salts in various industries (batteries, pyrochemical reprocessing of nuclear fuel, synthesis and catalysis). The basic concepts of the structure, dynamics, electrochemistry, interfacial and thermodynamic properties are detailed and relevant experimental methods described. Such fundamental concepts are essential for an in-depth understanding of the physicochemical properties of molten salts in general, including metal-molten salts, glass forming and low temperature melts. Experimental methods for investigating structural, dynamical, electrochemical thermodynamical and interfacial properties are detailed, as also are techniques for data collection and analysis. Scientists, engineers and technologists will find the volume a valuable reference source covering a wide spectrum of fundamental concepts and modern technologies.
This book contains proceedings of an international symposium on Atomistic th Simulation of Materials: Beyond Pair Potentials which was held in Chicago from the 25 th to 30 of September 1988, in conjunction with the ASM World Materials Congress. This symposium was financially supported by the Energy Conversion and Utilization Technology Program of the U. S Department of Energy and by the Air Force Office of Scientific Research. A total of fifty four talks were presented of which twenty one were invited. Atomistic simulations are now common in materials research. Such simulations are currently used to determine the structural and thermodynamic properties of crystalline solids, glasses and liquids. They are of particular importance in studies of crystal defects, interfaces and surfaces since their structures and behavior playa dominant role in most materials properties. The utility of atomistic simulations lies in their ability to provide information on those length scales where continuum theory breaks down and instead complex many body problems have to be solved to understand atomic level structures and processes.
This symposium was dedicated to the significant and ground breaking accomplishments of Robert A. Osteryoung in the area of molten salts and ionic liquids. This symposium provided an international and interdisciplinary forum centered on innovative basic and applied research performed in molten salts and ionic liquids. Contributed papers were solicited in all areas of biology, chemistry, electrochemistry, electrochemical engineering, and physics related to molten salt research.
Considering the properties of inorganic and organic ions pertaining directly, as well as indirectly, to their behaviour in solutions, this work aims to enable the specialist and non-specialist alike to comprehend ion behaviour in ongoing and developing studies and applications. The companion disk is for use with Microsoft Access 2.0.
Bosons are particles which form totally-symmetric composite quantum states. As a result, they obey Bose-Einstein statistics. The spin-statistics theorem states that bosons have integer spin. Bosons are also the only particles which can occupy the same state as another. All elementary particles are either bosons or fermions. Gauge bosons are elementary particles which act as the carriers of the fundamental forces such as the W vector bosons of the weak force, the gluons of the strong force, the photons of the electromagnetic force, and the graviton of the gravitational force. Particles composed of a number of other particles (such as protons or nuclei) can be either fermions or bosons, depend...
Six years passed by since the NATO ASI on "Liquid and Amorphous Metals" was held in Zwiesel, Germany, in September 1979. The present one is the second NATO School devoted to research on disordered condensed matter, mainly liquid and amorphous metals. This time the title contains the word "materials" to explicitely include those aspects of the glassy state of insulators either shared with metallic glasses - e.g. the glass tran sition - or on the border line with metallic systems - e.g. the metal non-metal transition. The long period which purposely elapsed between the two Institutes indi cates the intention not to have "just another conference", but to review the state of affairs in the field...
This volume on the novelties in the electronic properties of solids appears in occasion of Franco Bassani sixtieth birthday, and is dedicated to honour a scientific activity which has contributed so much of the development of this very active area of research. It is re markable that this book can cover so large a part of the current research on electronic properties of solids by contributions from Bassani's former students, collaborators at different stages of his scientific life, and physicists from all over the world who have been in close scientific relationship with him. A personal flavour therefore accompanies a number of the papers of this volume, which are both up-to-date reports on p...
The Advanced Study Institute on Strongly Coupled Plasmas was held on the campus of the Universite d'Orleans, Orleans-la-Source, France, from July 6th through July 23rd, 1977. 15 invited lecturers and 50 other participants attended the Institute. The present Volume contains the texts of most of the lectures and of some of the numerous seminars presented at the Institute. The topic of strongly coupled coulomb-systems has been an area of vigorous activities over the last few years. Such systems occur in a great variety of physical situations: stellar and planetary interiors, solid and liquid metals, semiconductors, laser compressed plasmas and gas discharges are some of the most important examp...