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The platinum-group elements (PGE) include platinum, palladium, rhodium, ruthenium, iridium and osmium. They are currently receiving world-wide attention as an attractive exploration target because they offer the dual attraction of rare, high value precious metals as well as major industrial applications. Platinum has aesthetic qualities, combined with a permanent lustre, which encourage its use in the manufacture of jewellery and, like gold, it also finds an investment role. Platinum, rhodium and palladium have important applications as catalysts, enabling petroleum and other fuels and chemicals to be produced efficiently from crude oil. This book gives a practical set of guidelines for impl...
This book describes and explains the methods by which three related ores and recyclables are made into high purity metals and chemicals, for materials processing. It focuses on present day processes and future developments rather than historical processes. Nickel, cobalt and platinum group metals are key elements for materials processing. They occur together in one book because they (i) map together on the periodic table (ii) occur together in many ores and (iii) are natural partners for further materials processing and materials manufacturing. They all are, for example, important catalysts – with platinum group metals being especially important for reducing car and truck emissions. Stainl...
The chemistry of platinum group metals is a rapidly expanding commercially important field. It is dominated by the catalytic properties of the metals. They are useful in petrochemical and general chemical plants and are becoming increasingly important as autocatalysts for pollution control. The book covers recent developments in the chemistry of the six platinum group metals, namely, platinum, palladium, rhodium, iridium, ruthenium and osmium. The material falls into three broad areas. Firstly, the occurrence, extraction and use of the metals, especially in catalysis, electrochemistry, energy and electronics. Secondly, organometallic and homogeneous catalytic chemistry and last but not least coordination chemistry including biochemistry and cancer therapy. The work is aimed at scientists in universities and in industry using any of the six platinum group metals in research. It will be useful for those studying the compounds of the metals themselves, and those considering to use either the metals or their complexes and catalysts in their experimental work.
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Since the implementation of catalysts containing platinum-group-elements (PGE) for the control of vehicle emissions in 1975, a controversial discussion has begun on PGE emissions and eventual consequences for the environment. However, a comprehensive overview of the various works and results in different scientific areas is still lacking. This book covers all aspects of anthropogenic PGE emissions and their consequences for man and environment. The interdisciplinary approach is substantiated by contributions from the fields of environmental geosciences, analytical chemistry, biology and occupational medicine. The articles mirror the actual status of scientific work and discuss environmentally related topics. Modern analytical methods for various environmental matrices as well as models of the current and future geochemical behaviour of PGE in the environment are presented. Bioavailability and toxicological and allergic potentials are discussed.
Like most supplement volumes of the platinum-group metal series,Platinum Suppl. Vol. A 1 has been written by an international team of specialists. It comprises technological data of all six platinum-group metals and their technically relevant alloys and compounds. The volume starts with a review on the recovery of the platinum-group metals (23 pages); the next 42 pages are devoted to processes for separating and refining the PGM in order to obtain metals of high purity. The electrodeposition of the PGM and their alloys is treated on 26 pages.The by far most extensive section deals with PGMand their alloys and compounds in catalysis. After a historicalsurvey and alist of important reviewson P...