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Molecular Water Oxidation Catalysis
Photocatalytic water splitting is a promising strategy for capturing energy from the sun by coupling light harvesting and the oxidation of water, in order to create clean hydrogen fuel. Thus a deep knowledge of the water oxidation catalysis field is essential to be able to come up with useful energy conversion devices based on sunlight and water splitting. Molecular Water Oxidation Catalysis: A Key Topic for New Sustainable Energy Conversion Schemes presents a comprehensive and state-of-the-art overview of water oxidation catalysis in homogeneous phase, describing in detail the most important catalysts discovered today based on first and second row transition metals. A strong emphasis is pla...
Energy Production and Storage
Energy production and storage are central problems for our time. In principle, abundant energy is available from the sun to run the earth in a sustainable way. Solar energy can be directly harnessed by agricultural and photovoltaic means, but the sheer scale of the energy demand poses severe challenges, for example any major competition between biomass production and food production would simply transfer scarcity from energy to food. Indirect use of solar energy in the form of wind looks also promising, especially for those regions not blessed with abundant sunlight. Other modes such as tidal and wave energy may well become important niche players. Inorganic chemistry plays a decisive role i...
The Economic History of Nuclear Energy in Spain
This book analyses the economic history of the nuclear program in Spain, from its inception in the 1950s to the nuclear moratorium in the early 1980s, and investigates the economic, financial and business origins of atomic energy in Spain. The actual dimension of the Spanish nuclear sector, which exceeded the relative economic and political clout of the country at the time, reflects the combination of domestic and foreign interests. Each contribution inserts the Spanish case within the international development of nuclear energy, but also shows how the Spanish nuclear program came about, how it was financed, and who the main architects and beneficiaries at the industrial, financial, commercial and banking levels were; all without losing sight of the energy policy aspects such as energy mix and energy security. The volume provides useful analysis and sources for a variety of core fields across the social sciences including economic history of post-war Europe, industrial and energy policy, international relations and history of technology.
New Ruthenium Complexes Containing N, P and S-donor Type of Ligands: Coordination Chemistry, Characterization and Application to Asymetric and Non-asymetric Catalysis
RESUM Síntesi de nous complexos de Ruteni amb lligands no quirals que tenen per fórmula [Ru(phen)([9]aneS3)X] (on X = H2O, py i MeCN). Caracterització espectroscòpica electroquímica i estructural daquesta família de complexos. Estudi de les seves propietats catalítiques en front a loxidació de substrats orgànics com lalcohol benzílic en reaccions delectrocatàlisi. Avaluació cinètica dels mecanismes de substitució entre els complexos Ru-py i Ru-MeCN. Generació dun interruptor molecular foto-induït. Síntesi de nous complexos quirals de Ru atropoisomèricament purs amb lligands oxazolínics que tenen per fórmula [Ru(trpy)(Ph-box-R)X] on (X = Cl, H2O, py, MeCN, 2-OH-py). Caract...
The Activation of Dioxygen and Homogeneous Catalytic Oxidation
This monograph consists of the proceedings of the Fifth International Symposium on the Activation of Dioxygen and Homogeneous Catalytic Oxidation, held in College Station, Texas, March 14-19, 1993. It contains an introductory chapter authored by Professors D. H. R. Barton and D. T. Sawyer, and twenty-nine chapters describing presentations by the plenary lecturers and invited speakers. One of the invited speakers, who could not submit a manuscript for reasons beyond his control, is represented by an abstract of his lecture. Also included are abstracts of forty-seven posters contributed by participants in the symposium. Readers who may wish to know more about the subjects presented in abstract...
Mononuclear and Heterotrinuclear Ruthenium Complexes
La fotosíntesis artificial constitueix una alternativa interessant al us de combustibles fòssils, i la reacció de oxidació de l'aigua és considerat el procés clau para la construcció d'un dispositiu capaç de realitzar-la. En aquest camp s'esta duent a terme una recerca exhaustiva per identificar les propietats i els mecanismes que defineixen un bon catalitzador d'oxidació d'aigua. Els complexes de ruteni han demostrat de ser-ne bons candidats. Aquest treball presenta la síntesis i la caracterització de múltiples complexes mononuclears i heterotrinuclears de ruteni, basats en dos lligants diferents. Les seves propietats han estat investigades amb mètodes de espectroscòpia i elec...
