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From the late-1960’s, perfluorosulfonic acid (PFSAs) ionomers have dominated the PEM fuel cell industry as the membrane material of choice. The “gold standard’ amongst the many variations that exist today has been, and to a great extent still is, DuPont’s Nafion® family of materials. However, there is significant concern in the industry that these materials will not meet the cost, performance, and durability requirementsnecessary to drive commercialization in key market segments – es- cially automotive. Indeed, Honda has already put fuel cell vehicles in the hands of real end users that have home-grown fuel cell stack technology incorporating hydrocarbon-based ionomers. “Polymer...
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J. Richard Biichi is well known for his work in mathematical logic and theoretical computer science. (He himself would have sharply objected to the qualifier "theoretical," because he more or less identified science and theory, using "theory" in a broader sense and "science" in a narrower sense than usual.) We are happy to present here this collection of his papers. I (DS)1 worked with Biichi for many years, on and off, ever since I did my Ph.D. thesis on his Sequential Calculus. His way was to travel locally, not globally: When we met we would try some specific problem, but rarely dis cussed research we had done or might do. After he died in April 1984 I sifted through the manuscripts and notes left behind and was dumbfounded to see what areas he had been in. Essentially I knew about his work in finite au tomata, monadic second-order theories, and computability. But here were at least four layers on his writing desk, and evidently he had been working on them all in parallel. I am sure that many people who knew Biichi would tell an analogous story.
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PEM Fuel Cell Failure Mode Analysis presents a systematic analysis of PEM fuel cell durability and failure modes. It provides readers with a fundamental understanding of insufficient fuel cell durability, identification of failure modes and failure mechanisms of PEM fuel cells, fuel cell component degradation testing, and mitigation strategies against degradation. The first several chapters of the book examine the degradation of various fuel cell components, including degradation mechanisms, the effects of operating conditions, mitigation strategies, and testing protocols. The book then discusses the effects of different contamination sources on the degradation of fuel cell components and ex...