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Oxidation and Antioxidants in Organic Chemistry and Biology
Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource. You will find up-to-date information
Inhibition of Chain Reactions
This text explores nonbranching reactions, including in-depth information on the inhibitors of free radical polymerisation and the mechanisms of antioxidants on oxidationprocesses. Auto-initiated chain reactions are also explored, with detailed descriptions on the kinetics, mechanisms, and inhibition of the autoxidation of organic compounds, A special chapter deals with the synergism of antioxidant actions. The theory of chain-branching reactions is investigated, and a large amount of new experimental data concerning the use of chemical additives to regulate combustion processes is also presented, including the mode of chain thermal explosion.
Recent Advances in Polymer Chemical Physics
The Institute of Chemical Physics of the Russian Academy of Sciences has become one of the world's premiere centers for studies of polymeric materials; in use, during processing, and in harsh environments. The Institute's focus is on commercially available materials and their modifications to improve performance through advanced theoretical analysis and implementation of experimental results. Selected papers from the Institute have been incorporated into five sections-Stabilization and Degradation, Biochemistry , Photochemistry, Rheology and Flame Retardancy-and should provide invaluable background to producers of polymeric materials.
PVC Degradation and Stabilization
PVC Degradation and Stabilization, Fifth Edition contains all the information necessary for the successful design of stabilization formulas in any PVC-based product. Other topics covered include degradation by thermal energy, UV, gamma, and other forms of radiation, chemical degradation, and more. Many new topics are of particular interest today, including new stabilization methods and mechanisms (e.g., synergistic mixtures containing hydrotalcites and their synthetic equivalents, beta-diketones, functionalized fillers, Shiff bases), new approaches to plasticization, methods of waste reprocessing (life cycle assessment, reformulation, biodegradable materials, and energy recovery), accelerate...
Mobility and Ancient Society in Asia and the Americas
Mobility and Ancient Society in Asia and the Americas contains contributions by leading international scholars concerning the character, timing, and geography of regional migrations that led to the dispersal of human societies from Inner and northeast Asia to the New World in the Upper Pleistocene (ca. 20,000-15,000 years ago). This volume bridges scholarly traditions from Europe, Central Asia, and North and South America, bringing different perspectives into a common view. The book presents an international overview of an ongoing discussion that is relevant to the ancient history of both Eurasia and the Americas. The content of the chapters provides both geographic and conceptual coverage o...
Quantitative Aspects of Polymer Stabilizers
Quantitative Aspects of Polymer Stabilizers
Principles of Polymerization
The new edition of a classic text and reference The large chains of molecules known as polymers are currently used in everything from "wash and wear" clothing to rubber tires to protective enamels and paints. Yet the practical applications of polymers are only increasing; innovations in polymer chemistry constantly bring both improved and entirely new uses for polymers onto the technological playing field. Principles of Polymerization, Fourth Edition presents the classic text on polymer synthesis, fully updated to reflect today's state of the art. New and expanded coverage in the Fourth Edition includes: * Metallocene and post-metallocene polymerization catalysts * Living polymerizations (ra...
Handbook of Free Radical Initiators
Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Antioxidative Stabilization Of Polymers
Polymers play a vital role in manufacturing processes of many kinds, and the development of new polymeric materials is of increasing importance in the field of materials science. Because of this, there is a need to understand why the properties of polymers change, what can be done to avoid degradation and failure, and how performance can be maintained over a much longer lifespan. The authors deal firstly with the process of degradation through oxidation, and then explain how the addition of various antioxidants can inhibit or retard this process. They present a unique discussion of the physico-chemical aspects, particularly the chemical kinetics of antioxidant action and of branched chain reaction kinetics, and the theory of critical phenomena inhibited oxidation. The last part of the book offers practical advice on methods of oxidation investigation, on selection of appropriate antixodants, and on the basic principles of performance prognosis. The book also includes a unique coverage of the regularities of additive solubility.
Pyrolysis of Organic Molecules
Pyrolysis of Organic Molecules with Applications to Health and Environmental Issues, the 28th volume in the Techniques and Instrumentation in Analytical Chemistry series, gives a systematic and comprehensive description of pyrolysis of non-polymeric organic molecules. Pyrolysis is involved in many practical applications as well as in many common human activities, but harmful compounds can be generated in the process. The study of pyrolysis and of the formation of undesirable compounds as a result of pyrolytic processes is of considerable interest to chemists, chemical engineers, and toxicologists. - Pyrolysis results for compounds not previously studied or reported - Updated information from a large body of results published on pyrolysis of individual compounds or classes of compounds - Information on mechanisms and kinetics of numerous pyrolytic processes
